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鲁彦 郭建宇 张祥民
毛细管高效液相色谱,毛细管整体柱,溶胶凝胶,制备,,毛细管高效液相色谱，毛细管整体柱，溶胶凝胶，制备,1引言,2实验部分,3结果与讨论,R
摘 要 在优化条件下成功制备了50 μm、75 μm、100 μm和200 μm等多种口径的硅胶基质毛细管液相色谱整体柱，克服了文献报道中常见的开裂、重现性差等缺点。考察了柱压降与流速的关系，以多环芳烃系列化合物评价了自制的C18硅胶基质毛细管液相色谱整体柱的色谱性能，在以甲醇水为流动相的反相色谱条件下，5种化合物(苯、萘、联萘、芴和蒽)得到了基线分离。该柱对萘的柱效达到了67000塔板/米。
关键词 毛细管高效液相色谱，毛细管整体柱，溶胶凝胶，制备
Preparation and Evaluation of ODS Monolithic
Silica Column for Capillary Liquid Chromatography
Lu Yan, Guo Jianyu, Zhang Xiangmin
(Department of Chemical Engineering, Shanghai Institute of Technology, Shanghai 200235)
(College of Life and Environment Sciences, Shanghai Normal University, Shanghai 200234) ......
关键词 毛细管高效液相色谱，毛细管整体柱，溶胶凝胶，制备
Preparation and Evaluation of ODS Monolithic
Silica Column for Capillary Liquid Chromatography
Lu Yan, Guo Jianyu, Zhang Xiangmin
(Department of Chemical Engineering, Shanghai Institute of Technology, Shanghai 200235)
(College of Life and Environment Sciences, Shanghai Normal University, Shanghai 200234) ......